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"Double Trouble (Team Rocket)" is the ninth song featured on the Pokémon album 2.B.A. Master. As the title suggests, it is sung by Jessie, James and Meowth of Team Rocket, with their boss Giovanni supplying two lines.
To promote the album's release, the song appeared as a short "Pikachu's Jukebox" music video at the end of the anime episodes "Beauty and the Beach", "The Purr-fect Hero", "The Pi-Kahuna", "Bad to the Bone", "Friend and Foe Alike", "The Lost Lapras", "Shell Shock", "A Shipful of Shivers", and "Get Along, Little Pokémon". The song was later used as background music in "A Lean Mean Team Rocket Machine".
In Pokémon Live!, Jessie and James sing a shorter version of the song with slightly altered lyrics, in which they tell Giovanni that they successfully stole Ash's Pikachu. They reprise the song a few minutes later when Giovanni orders them to go capture Pikachu's trainer.
An instrumental version of the song is used as Team Rocket's theme music in Pokémon Puzzle League.